Crystal Field Theory
Octahedral Complex d-Orbital Splitting
X
Y
Z
Governing Equations
CFSE = nt2g x (-0.4Δo) + neg x (+0.6Δo)
μeff = √(n(n+2)) BM
μeff = √(n(n+2)) BM
CFSE
-0.4
Δo
Unpaired e⁻
4
n
Magnetic Moment
4.90
BM
Spin State
HIGH SPIN
Electron Configuration
-0.4Δo
+0.6Δo
eg
t2g
Central Metal
Ligands
t2g orbitals
eg orbitals